The first triple-decker complex with the PtMe <inf>3</inf> fragment: CpCo(μ-1,3-C <inf>3</inf>B <inf>2</inf>Me <inf>5</inf>)PtMe <inf>3</inf>

A.S. Romanov; D.V. Muratov; P.V. Petrovskii; W. Siebert; A.R. Kudinov

doi:10.1016/j.mencom.2012.01.004

The first triple-decker complex with the PtMe <inf>3</inf> fragment: CpCo(μ-1,3-C <inf>3</inf>B <inf>2</inf>Me <inf>5</inf>)PtMe <inf>3</inf>

A.S. Romanov, D.V. Muratov, P.V. Petrovskii, W. Siebert, A.R. Kudinov

Materials Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The μ-diborolyl triple-decker complex CpCo(μ-1,3-C 3B 2Me 5)PtMe 3 was prepared by reaction of the sandwich anion [CpCo(1,3-C 3B 2Me 5)]-with [PtMe 3I] 4; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C 3B 2Me 5)]- and [PtMe3]+ fragments are ∼64% electrostatic and 36% covalent.

Original language	English
Pages (from-to)	13-14
Number of pages	2
Journal	Mendeleev Communications
Volume	22
Issue number	1
DOIs	https://doi.org/10.1016/j.mencom.2012.01.004
Publication status	Published - Jan 2012

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title = "The first triple-decker complex with the PtMe 3 fragment: CpCo(μ-1,3-C 3B 2Me 5)PtMe 3",

abstract = "The μ-diborolyl triple-decker complex CpCo(μ-1,3-C 3B 2Me 5)PtMe 3 was prepared by reaction of the sandwich anion [CpCo(1,3-C 3B 2Me 5)]-with [PtMe 3I] 4; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C 3B 2Me 5)]- and [PtMe3]+ fragments are ∼64% electrostatic and 36% covalent.",

author = "A.S. Romanov and D.V. Muratov and P.V. Petrovskii and W. Siebert and A.R. Kudinov",

year = "2012",

month = jan,

doi = "10.1016/j.mencom.2012.01.004",

language = "English",

volume = "22",

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AU - Romanov, A.S.

AU - Muratov, D.V.

AU - Petrovskii, P.V.

AU - Siebert, W.

AU - Kudinov, A.R.

PY - 2012/1

Y1 - 2012/1

N2 - The μ-diborolyl triple-decker complex CpCo(μ-1,3-C 3B 2Me 5)PtMe 3 was prepared by reaction of the sandwich anion [CpCo(1,3-C 3B 2Me 5)]-with [PtMe 3I] 4; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C 3B 2Me 5)]- and [PtMe3]+ fragments are ∼64% electrostatic and 36% covalent.

AB - The μ-diborolyl triple-decker complex CpCo(μ-1,3-C 3B 2Me 5)PtMe 3 was prepared by reaction of the sandwich anion [CpCo(1,3-C 3B 2Me 5)]-with [PtMe 3I] 4; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C 3B 2Me 5)]- and [PtMe3]+ fragments are ∼64% electrostatic and 36% covalent.

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U2 - 10.1016/j.mencom.2012.01.004

DO - 10.1016/j.mencom.2012.01.004

M3 - Article

SN - 0959-9436

VL - 22

SP - 13

EP - 14

JO - Mendeleev Communications

JF - Mendeleev Communications

IS - 1

ER -

The first triple-decker complex with the PtMe <inf>3</inf> fragment: CpCo(μ-1,3-C <inf>3</inf>B <inf>2</inf>Me <inf>5</inf>)PtMe <inf>3</inf>

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