The fragmentation of doubly charged methanol

Bernard Treves Brown; J. H D Eland; B. J. Treves-Brown

doi:10.1016/0168-1176(92)80029-Z

The fragmentation of doubly charged methanol

Bernard Treves Brown
, J. H D Eland
, B. J. Treves-Brown

Research output: Contribution to journal › Article › peer-review

Abstract

Doubly charged methanol ions formed by photoionization at vacuum ultraviolet wavelengths decay mainly by fast charge separation along a large number of pathways. The major reactions involve sequential, not concerted processes, with little hydrogen scrambling. The species CH2OH2+ and CHOH2+ are observed as relatively long-lived intermediates with mean lifetimes between 10 and 100 ns. © 1992.

Original language	English
Pages (from-to)	167-176
Number of pages	9
Journal	International Journal of Mass Spectrometry and Ion Processes
Volume	113
Issue number	2
DOIs	https://doi.org/10.1016/0168-1176(92)80029-Z
Publication status	Published - 2 Mar 1992

Keywords

charge separation reactions
ion fragmentation mechanisms
methanol ions
PEPIPICO spectra

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10.1016/0168-1176(92)80029-Z

Cite this

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title = "The fragmentation of doubly charged methanol",

abstract = "Doubly charged methanol ions formed by photoionization at vacuum ultraviolet wavelengths decay mainly by fast charge separation along a large number of pathways. The major reactions involve sequential, not concerted processes, with little hydrogen scrambling. The species CH2OH2+ and CHOH2+ are observed as relatively long-lived intermediates with mean lifetimes between 10 and 100 ns. {\textcopyright} 1992.",

keywords = "charge separation reactions, ion fragmentation mechanisms, methanol ions, PEPIPICO spectra",

author = "\{Treves Brown\}, Bernard and Eland, \{J. H D\} and Treves-Brown, \{B. J.\}",

year = "1992",

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doi = "10.1016/0168-1176(92)80029-Z",

language = "English",

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journal = "International Journal of Mass Spectrometry and Ion Processes",

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T1 - The fragmentation of doubly charged methanol

AU - Treves Brown, Bernard

AU - Eland, J. H D

AU - Treves-Brown, B. J.

PY - 1992/3/2

Y1 - 1992/3/2

N2 - Doubly charged methanol ions formed by photoionization at vacuum ultraviolet wavelengths decay mainly by fast charge separation along a large number of pathways. The major reactions involve sequential, not concerted processes, with little hydrogen scrambling. The species CH2OH2+ and CHOH2+ are observed as relatively long-lived intermediates with mean lifetimes between 10 and 100 ns. © 1992.

AB - Doubly charged methanol ions formed by photoionization at vacuum ultraviolet wavelengths decay mainly by fast charge separation along a large number of pathways. The major reactions involve sequential, not concerted processes, with little hydrogen scrambling. The species CH2OH2+ and CHOH2+ are observed as relatively long-lived intermediates with mean lifetimes between 10 and 100 ns. © 1992.

KW - charge separation reactions

KW - ion fragmentation mechanisms

KW - methanol ions

KW - PEPIPICO spectra

U2 - 10.1016/0168-1176(92)80029-Z

DO - 10.1016/0168-1176(92)80029-Z

M3 - Article

SN - 0168-1176

VL - 113

SP - 167

EP - 176

JO - International Journal of Mass Spectrometry and Ion Processes

JF - International Journal of Mass Spectrometry and Ion Processes

IS - 2

ER -

The fragmentation of doubly charged methanol

Abstract

Keywords

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