Abstract
Sulphur has been recognised as a growth promoter for carbon fibres and carbon nanotubes for over 30 years. Moreover, the Fe-C-S system, in particular, has been extensively studied for more than half a century in the fields of steelmaking and cast iron. In the present work we examine the role of sulphur in the iron-catalysed growth of carbon nanotubes during the process of direct spinning of fibres from the gas phase. A detailed microstructural characterisation of the reaction products was conducted by high resolution TEM and EELS composition mapping on a dedicated FEG STEM (VG HB 501) equipped with C s aberration correctors. Our results agree with previous works in classical metallurgy, indicating that sulphur forms a layer on the surface of the catalyst particles that plays a role in encouraging nanotube growth by surface diffusion. Copyright © 2008 American Scientific Publishers All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 2442-2449 |
| Number of pages | 7 |
| Journal | Journal of Nanoscience and Nanotechnology |
| Volume | 8 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - May 2008 |
Keywords
- Carbon nanotubes
- CVD
- Sulphur
- Synthesis