The structural influence in the stability of polymer-bound diazonium salts

Stefan Bräse; Stefan Dahmen; Crisan Popescu; Maarten Schroen; Franz Wortmann

doi:10.1002/chem.200400386

The structural influence in the stability of polymer-bound diazonium salts

Stefan Bräse, Stefan Dahmen, Crisan Popescu, Maarten Schroen, Franz Wortmann

Research output: Contribution to journal › Article › peer-review

Abstract

Various new diazonium ions on a polymeric support that have a variety of counterions and complexation with crown ethers have been prepared, and the thermal stability of these resins over a larger temperature interval has been investigated. Nonisothermal kinetics applied to DSC data have been used predicting the lifetime of the resins.

Original language	English
Pages (from-to)	5285-5296
Number of pages	11
Journal	Chemistry - A European Journal
Volume	10
Issue number	21
DOIs	https://doi.org/10.1002/chem.200400386
Publication status	Published - 25 Oct 2004

Keywords

Azo compounds
Differential scanning calorimetry
Kinetics
Resins
Solid supports

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title = "The structural influence in the stability of polymer-bound diazonium salts",

abstract = "Various new diazonium ions on a polymeric support that have a variety of counterions and complexation with crown ethers have been prepared, and the thermal stability of these resins over a larger temperature interval has been investigated. Nonisothermal kinetics applied to DSC data have been used predicting the lifetime of the resins.",

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author = "Stefan Br{\"a}se and Stefan Dahmen and Crisan Popescu and Maarten Schroen and Franz Wortmann",

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AU - Bräse, Stefan

AU - Dahmen, Stefan

AU - Popescu, Crisan

AU - Schroen, Maarten

AU - Wortmann, Franz

PY - 2004/10/25

Y1 - 2004/10/25

N2 - Various new diazonium ions on a polymeric support that have a variety of counterions and complexation with crown ethers have been prepared, and the thermal stability of these resins over a larger temperature interval has been investigated. Nonisothermal kinetics applied to DSC data have been used predicting the lifetime of the resins.

AB - Various new diazonium ions on a polymeric support that have a variety of counterions and complexation with crown ethers have been prepared, and the thermal stability of these resins over a larger temperature interval has been investigated. Nonisothermal kinetics applied to DSC data have been used predicting the lifetime of the resins.

KW - Azo compounds

KW - Differential scanning calorimetry

KW - Kinetics

KW - Resins

KW - Solid supports

U2 - 10.1002/chem.200400386

DO - 10.1002/chem.200400386

M3 - Article

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SP - 5285

EP - 5296

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 21

ER -

The structural influence in the stability of polymer-bound diazonium salts

Abstract

Keywords

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