The synthesis and single-crystal X-ray structure of the tetranuclear silver(I) complex [Ag2([18]aneS2O4) 2]2 (PF6)4 ([18]aneS 2O4 = 1,4,7, 10-tetraoxa-13, 16-dithiacyclooctadecane)

Martin Schroder, A J Blake, R O Gould, C Radek, M Schröder

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Reaction of AgNO3 with [18]aneS2O4([18]aneS2O4= 1,4,7,10-tetraoxa-13, 16-dithiacyclooctadecane) affords a 1 : 1 complex, the single-crystal X-ray structure of which confirms the formation of binuclear [Ag2([18]aneS2O4)2]2+ dications; these dications are linked in pairs by a long S ⋯ S interaction to give an overall tetranuclear structure.
    Original languageEnglish
    Pages (from-to)985-986
    Number of pages2
    JournalChemical Communications
    Issue number8
    DOIs
    Publication statusPublished - 1994

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