The synthesis and structural characterisation of an homologous series of group 14 1-chloro-2,2-difluorovinyl compounds

Alan K. Brisdon; I. R. Crossley; J. A. Greenall; R. G. Pritchard; J. E. Warren

doi:10.1016/j.jfluchem.2004.01.025

The synthesis and structural characterisation of an homologous series of group 14 1-chloro-2,2-difluorovinyl compounds

Alan K. Brisdon, I. R. Crossley, J. A. Greenall, R. G. Pritchard, J. E. Warren

Research output: Contribution to journal › Article › peer-review

Abstract

A series of group 14 1-chloro-2,2-difluorovinyl compounds Ph3 E(CCl=CF2) (E=Ge, Sn, Pb) has been prepared using the low temperature reactions of 1-chloro-2,2-difluorovinyllithium (LiCCl=CF2), generated in situ from CF3 CH2Cl (HCFC-133a) and n-butyllithium. These new materials have been fully characterised, including for E=Ge and Sn, by single crystal X-ray studies. This is the first time that any main-group 1-chloro-2,2-difluorovinyl compounds have been crystallographically studied. © 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	1099-1103
Number of pages	4
Journal	Journal of Fluorine Chemistry
Volume	125
Issue number	7
DOIs	https://doi.org/10.1016/j.jfluchem.2004.01.025
Publication status	Published - Jul 2004

Keywords

Chlorodifluorovinyl
HCFC-133a
Main-group
Organometallic
Structural
Synthesis
Vinyl

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10.1016/j.jfluchem.2004.01.025

CCDC 228474: Experimental Crystal Structure Determination
Brisdon, A. (Contributor), Crossley, I. R. (Contributor), Greenall, J. A. (Contributor), Pritchard, R. (Contributor) & Warren, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2004
DOI: 10.5517/cc7nr4r, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7nr4r&sid=DataCite
Dataset
CCDC 228473: Experimental Crystal Structure Determination
Brisdon, A. (Contributor), Crossley, I. R. (Contributor), Greenall, J. A. (Contributor), Pritchard, R. (Contributor) & Warren, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2004
DOI: 10.5517/cc7nr3q, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7nr3q&sid=DataCite
Dataset

Cite this

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title = "The synthesis and structural characterisation of an homologous series of group 14 1-chloro-2,2-difluorovinyl compounds",

abstract = "A series of group 14 1-chloro-2,2-difluorovinyl compounds Ph3 E(CCl=CF2) (E=Ge, Sn, Pb) has been prepared using the low temperature reactions of 1-chloro-2,2-difluorovinyllithium (LiCCl=CF2), generated in situ from CF3 CH2Cl (HCFC-133a) and n-butyllithium. These new materials have been fully characterised, including for E=Ge and Sn, by single crystal X-ray studies. This is the first time that any main-group 1-chloro-2,2-difluorovinyl compounds have been crystallographically studied. {\textcopyright} 2004 Elsevier B.V. All rights reserved.",

keywords = "Chlorodifluorovinyl, HCFC-133a, Main-group, Organometallic, Structural, Synthesis, Vinyl",

author = "Brisdon, {Alan K.} and Crossley, {I. R.} and Greenall, {J. A.} and Pritchard, {R. G.} and Warren, {J. E.}",

note = "7",

year = "2004",

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doi = "10.1016/j.jfluchem.2004.01.025",

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volume = "125",

pages = "1099--1103",

journal = "Journal of Fluorine Chemistry",

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TY - JOUR

T1 - The synthesis and structural characterisation of an homologous series of group 14 1-chloro-2,2-difluorovinyl compounds

AU - Brisdon, Alan K.

AU - Crossley, I. R.

AU - Greenall, J. A.

AU - Pritchard, R. G.

AU - Warren, J. E.

N1 - 7

PY - 2004/7

Y1 - 2004/7

N2 - A series of group 14 1-chloro-2,2-difluorovinyl compounds Ph3 E(CCl=CF2) (E=Ge, Sn, Pb) has been prepared using the low temperature reactions of 1-chloro-2,2-difluorovinyllithium (LiCCl=CF2), generated in situ from CF3 CH2Cl (HCFC-133a) and n-butyllithium. These new materials have been fully characterised, including for E=Ge and Sn, by single crystal X-ray studies. This is the first time that any main-group 1-chloro-2,2-difluorovinyl compounds have been crystallographically studied. © 2004 Elsevier B.V. All rights reserved.

AB - A series of group 14 1-chloro-2,2-difluorovinyl compounds Ph3 E(CCl=CF2) (E=Ge, Sn, Pb) has been prepared using the low temperature reactions of 1-chloro-2,2-difluorovinyllithium (LiCCl=CF2), generated in situ from CF3 CH2Cl (HCFC-133a) and n-butyllithium. These new materials have been fully characterised, including for E=Ge and Sn, by single crystal X-ray studies. This is the first time that any main-group 1-chloro-2,2-difluorovinyl compounds have been crystallographically studied. © 2004 Elsevier B.V. All rights reserved.

KW - Chlorodifluorovinyl

KW - HCFC-133a

KW - Main-group

KW - Organometallic

KW - Structural

KW - Synthesis

KW - Vinyl

U2 - 10.1016/j.jfluchem.2004.01.025

DO - 10.1016/j.jfluchem.2004.01.025

M3 - Article

SN - 0022-1139

VL - 125

SP - 1099

EP - 1103

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 7

ER -

The synthesis and structural characterisation of an homologous series of group 14 1-chloro-2,2-difluorovinyl compounds

Abstract

Keywords

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Datasets

CCDC 228474: Experimental Crystal Structure Determination

CCDC 228473: Experimental Crystal Structure Determination

Cite this