The synthesis, spectroscopy and X-ray single crystal structure of catena-[(μ-anacardato)-copper(ii)bipyridine][Cu2{(μ-O 2CC6H3(o-OH)(o-C15H 31)}4(NC5H5)2]

Mohammad Azad Malik; Paul O'Brien; Floriana Tuna; Robin Pritchard; Joseph Buchweishaija; Elianaso Kimambo; Egid B. Mubofu

doi:10.1039/c3dt51634b

The synthesis, spectroscopy and X-ray single crystal structure of catena-[(μ-anacardato)-copper(ii)bipyridine][Cu2{(μ-O 2CC6H3(o-OH)(o-C15H 31)}4(NC5H5)2]

Mohammad Azad Malik, Paul O'Brien, Floriana Tuna, Robin Pritchard, Joseph Buchweishaija, Elianaso Kimambo, Egid B. Mubofu

Research output: Contribution to journal › Article › peer-review

Abstract

Hydrogenation of crude anacardic acid gave a transparent crystalline product on recrystallization. When reacted with copper nitrate in the presence of pyridine it produced green crystals of a pyridine adduct of a dimeric copper(ii) anacardate with the copper acetate structure. The X-ray single crystal structures of both anacardic acid and the copper complex were determined. Magnetic studies have confirmed strong antiferromagnetic coupling between copper(ii) centre in the dimer. The exchange coupling constant was determined to be J = -324 cm-1. The EPR spectra of the polycrystalline product are consistent with spin S = 1. The zero-field splitting parameter and g tensor values are D = 0.36 cm-1, g = 2.36 and g = 2.06. © 2013 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	14438-14444
Number of pages	6
Journal	Dalton Transactions
Volume	42
Issue number	40
DOIs	https://doi.org/10.1039/c3dt51634b
Publication status	Published - 28 Oct 2013

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10.1039/c3dt51634b

CCDC 877508: Experimental Crystal Structure Determination
Malik, M. (Contributor), O'Brien, P. (Contributor), Tuna, F. (Contributor), Pritchard, R. (Contributor), Buchweishaija, J. (Contributor), Kimambo, E. (Contributor) & Mubofu, E. B. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/ccyg3q6, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccyg3q6&sid=DataCite
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CCDC 877555: Experimental Crystal Structure Determination
Malik, M. (Contributor), O'Brien, P. (Contributor), Tuna, F. (Contributor), Pritchard, R. (Contributor), Buchweishaija, J. (Contributor), Kimambo, E. (Contributor) & Mubofu, E. B. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/ccyg57s, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccyg57s&sid=DataCite
Dataset

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@article{508c26759f6742e0b0359f571abde206,

title = "The synthesis, spectroscopy and X-ray single crystal structure of catena-[(μ-anacardato)-copper(ii)bipyridine][Cu2\{(μ-O 2CC6H3(o-OH)(o-C15H 31)\}4(NC5H5)2]",

abstract = "Hydrogenation of crude anacardic acid gave a transparent crystalline product on recrystallization. When reacted with copper nitrate in the presence of pyridine it produced green crystals of a pyridine adduct of a dimeric copper(ii) anacardate with the copper acetate structure. The X-ray single crystal structures of both anacardic acid and the copper complex were determined. Magnetic studies have confirmed strong antiferromagnetic coupling between copper(ii) centre in the dimer. The exchange coupling constant was determined to be J = -324 cm-1. The EPR spectra of the polycrystalline product are consistent with spin S = 1. The zero-field splitting parameter and g tensor values are D = 0.36 cm-1, g = 2.36 and g = 2.06. {\textcopyright} 2013 The Royal Society of Chemistry.",

author = "Malik, \{Mohammad Azad\} and Paul O'Brien and Floriana Tuna and Robin Pritchard and Joseph Buchweishaija and Elianaso Kimambo and Mubofu, \{Egid B.\}",

year = "2013",

month = oct,

day = "28",

doi = "10.1039/c3dt51634b",

language = "English",

volume = "42",

pages = "14438--14444",

journal = "Dalton Transactions",

issn = "1477-9234",

publisher = "Royal Society of Chemistry",

number = "40",

}

TY - JOUR

T1 - The synthesis, spectroscopy and X-ray single crystal structure of catena-[(μ-anacardato)-copper(ii)bipyridine][Cu2{(μ-O 2CC6H3(o-OH)(o-C15H 31)}4(NC5H5)2]

AU - Malik, Mohammad Azad

AU - O'Brien, Paul

AU - Tuna, Floriana

AU - Pritchard, Robin

AU - Buchweishaija, Joseph

AU - Kimambo, Elianaso

AU - Mubofu, Egid B.

PY - 2013/10/28

Y1 - 2013/10/28

N2 - Hydrogenation of crude anacardic acid gave a transparent crystalline product on recrystallization. When reacted with copper nitrate in the presence of pyridine it produced green crystals of a pyridine adduct of a dimeric copper(ii) anacardate with the copper acetate structure. The X-ray single crystal structures of both anacardic acid and the copper complex were determined. Magnetic studies have confirmed strong antiferromagnetic coupling between copper(ii) centre in the dimer. The exchange coupling constant was determined to be J = -324 cm-1. The EPR spectra of the polycrystalline product are consistent with spin S = 1. The zero-field splitting parameter and g tensor values are D = 0.36 cm-1, g = 2.36 and g = 2.06. © 2013 The Royal Society of Chemistry.

AB - Hydrogenation of crude anacardic acid gave a transparent crystalline product on recrystallization. When reacted with copper nitrate in the presence of pyridine it produced green crystals of a pyridine adduct of a dimeric copper(ii) anacardate with the copper acetate structure. The X-ray single crystal structures of both anacardic acid and the copper complex were determined. Magnetic studies have confirmed strong antiferromagnetic coupling between copper(ii) centre in the dimer. The exchange coupling constant was determined to be J = -324 cm-1. The EPR spectra of the polycrystalline product are consistent with spin S = 1. The zero-field splitting parameter and g tensor values are D = 0.36 cm-1, g = 2.36 and g = 2.06. © 2013 The Royal Society of Chemistry.

U2 - 10.1039/c3dt51634b

DO - 10.1039/c3dt51634b

M3 - Article

SN - 1477-9234

VL - 42

SP - 14438

EP - 14444

JO - Dalton Transactions

JF - Dalton Transactions

IS - 40

ER -

The synthesis, spectroscopy and X-ray single crystal structure of catena-[(μ-anacardato)-copper(ii)bipyridine][Cu2{(μ-O 2CC6H3(o-OH)(o-C15H 31)}4(NC5H5)2]

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Datasets

CCDC 877508: Experimental Crystal Structure Determination

CCDC 877555: Experimental Crystal Structure Determination

Cite this