Thermal and photooxidation of high styrene-butadiene copolymer (SBC)

Norman S. Allen; Adriana Barcelona; Michele Edge; Arthur Wilkinson; Carmen Galan Merchan; V. Ruiz Santa Quiteria

doi:10.1016/j.polymdegradstab.2003.10.010

Thermal and photooxidation of high styrene-butadiene copolymer (SBC)

Norman S. Allen, Adriana Barcelona, Michele Edge, Arthur Wilkinson, Carmen Galan Merchan, V. Ruiz Santa Quiteria

Research output: Contribution to journal › Article › peer-review

Abstract

The study of thermal properties and photooxidation of high styrene-butadiene copolymer (SBC) with high styrene content (K-resin) using a variety of analytical and spectroscopic methods including yellowness, luminescence and FTIR spectroscopy. It was observed that the FTIR and luminescence analysis show complex oxidation processes with some distinct features associated with each phase. It was shown that the rates of thermal oxidation on oven ageing increases carbonyl growth with increasing temperature. The autocatalytic growth and decay of hydroperoxides at 110 and 90°C with high concentrations being observed at 90°C were observed.

Original language	English
Pages (from-to)	11-23
Number of pages	12
Journal	Polymer Degradation and Stability
Volume	86
Issue number	1
DOIs	https://doi.org/10.1016/j.polymdegradstab.2003.10.010
Publication status	Published - Oct 2004

Keywords

Elastomers
Infra-red analysis
Luminescence
Photooxidation
SBC-resins
Styrene-butadiene copolymer
Thermal oxidation

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10.1016/j.polymdegradstab.2003.10.010

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title = "Thermal and photooxidation of high styrene-butadiene copolymer (SBC)",

abstract = "The study of thermal properties and photooxidation of high styrene-butadiene copolymer (SBC) with high styrene content (K-resin) using a variety of analytical and spectroscopic methods including yellowness, luminescence and FTIR spectroscopy. It was observed that the FTIR and luminescence analysis show complex oxidation processes with some distinct features associated with each phase. It was shown that the rates of thermal oxidation on oven ageing increases carbonyl growth with increasing temperature. The autocatalytic growth and decay of hydroperoxides at 110 and 90°C with high concentrations being observed at 90°C were observed.",

keywords = "Elastomers, Infra-red analysis, Luminescence, Photooxidation, SBC-resins, Styrene-butadiene copolymer, Thermal oxidation",

author = "Allen, {Norman S.} and Adriana Barcelona and Michele Edge and Arthur Wilkinson and Merchan, {Carmen Galan} and Quiteria, {V. Ruiz Santa}",

year = "2004",

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doi = "10.1016/j.polymdegradstab.2003.10.010",

language = "English",

volume = "86",

pages = "11--23",

journal = "Polymer Degradation and Stability",

issn = "0141-3910",

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TY - JOUR

T1 - Thermal and photooxidation of high styrene-butadiene copolymer (SBC)

AU - Allen, Norman S.

AU - Barcelona, Adriana

AU - Edge, Michele

AU - Wilkinson, Arthur

AU - Merchan, Carmen Galan

AU - Quiteria, V. Ruiz Santa

PY - 2004/10

Y1 - 2004/10

N2 - The study of thermal properties and photooxidation of high styrene-butadiene copolymer (SBC) with high styrene content (K-resin) using a variety of analytical and spectroscopic methods including yellowness, luminescence and FTIR spectroscopy. It was observed that the FTIR and luminescence analysis show complex oxidation processes with some distinct features associated with each phase. It was shown that the rates of thermal oxidation on oven ageing increases carbonyl growth with increasing temperature. The autocatalytic growth and decay of hydroperoxides at 110 and 90°C with high concentrations being observed at 90°C were observed.

AB - The study of thermal properties and photooxidation of high styrene-butadiene copolymer (SBC) with high styrene content (K-resin) using a variety of analytical and spectroscopic methods including yellowness, luminescence and FTIR spectroscopy. It was observed that the FTIR and luminescence analysis show complex oxidation processes with some distinct features associated with each phase. It was shown that the rates of thermal oxidation on oven ageing increases carbonyl growth with increasing temperature. The autocatalytic growth and decay of hydroperoxides at 110 and 90°C with high concentrations being observed at 90°C were observed.

KW - Elastomers

KW - Infra-red analysis

KW - Luminescence

KW - Photooxidation

KW - SBC-resins

KW - Styrene-butadiene copolymer

KW - Thermal oxidation

U2 - 10.1016/j.polymdegradstab.2003.10.010

DO - 10.1016/j.polymdegradstab.2003.10.010

M3 - Article

VL - 86

SP - 11

EP - 23

JO - Polymer Degradation and Stability

JF - Polymer Degradation and Stability

SN - 0141-3910

IS - 1

ER -

Thermal and photooxidation of high styrene-butadiene copolymer (SBC)

Abstract

Keywords

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