Thick coating and functionalization of organic surfaces via ATRP in water

Debora Bontempo; Nicola Tirelli; Giancarlo Masci; Vittorio Crescenzi; Joffrey A. Hubbell

doi:10.1002/1521-3927(20020401)23:7<417::AID-MARC417>3.0.CO;2-3

Thick coating and functionalization of organic surfaces via ATRP in water

Debora Bontempo, Nicola Tirelli, Giancarlo Masci, Vittorio Crescenzi, Joffrey A. Hubbell

Research output: Contribution to journal › Article › peer-review

Abstract

Atom-transfer radical polymerization has been used for polymerizing water-soluble monomers from solid polymeric particles, intended as a model for any polymeric functional surface. Depending on the polarity of substrate and solvent, homogeneous initiation throughout the particles or pure surface initiation could be obtained. In the last case, polymer layers were obtained with thickness up to several tens of microns, still active for block copolymerization.

Original language	English
Pages (from-to)	417-422
Number of pages	5
Journal	Macromolecular rapid communications
Volume	23
Issue number	7
DOIs	https://doi.org/10.1002/1521-3927(20020401)23:7<417::AID-MARC417>3.0.CO;2-3
Publication status	Published - 6 May 2002

Keywords

Atom transfer radical polymerization (ATRP)
Biocompatibility
Films
Surface polymerization

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10.1002/1521-3927(20020401)23:7<417::AID-MARC417>3.0.CO;2-3

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title = "Thick coating and functionalization of organic surfaces via ATRP in water",

abstract = "Atom-transfer radical polymerization has been used for polymerizing water-soluble monomers from solid polymeric particles, intended as a model for any polymeric functional surface. Depending on the polarity of substrate and solvent, homogeneous initiation throughout the particles or pure surface initiation could be obtained. In the last case, polymer layers were obtained with thickness up to several tens of microns, still active for block copolymerization.",

keywords = "Atom transfer radical polymerization (ATRP), Biocompatibility, Films, Surface polymerization",

author = "Debora Bontempo and Nicola Tirelli and Giancarlo Masci and Vittorio Crescenzi and Hubbell, {Joffrey A.}",

year = "2002",

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T1 - Thick coating and functionalization of organic surfaces via ATRP in water

AU - Bontempo, Debora

AU - Tirelli, Nicola

AU - Masci, Giancarlo

AU - Crescenzi, Vittorio

AU - Hubbell, Joffrey A.

PY - 2002/5/6

Y1 - 2002/5/6

N2 - Atom-transfer radical polymerization has been used for polymerizing water-soluble monomers from solid polymeric particles, intended as a model for any polymeric functional surface. Depending on the polarity of substrate and solvent, homogeneous initiation throughout the particles or pure surface initiation could be obtained. In the last case, polymer layers were obtained with thickness up to several tens of microns, still active for block copolymerization.

AB - Atom-transfer radical polymerization has been used for polymerizing water-soluble monomers from solid polymeric particles, intended as a model for any polymeric functional surface. Depending on the polarity of substrate and solvent, homogeneous initiation throughout the particles or pure surface initiation could be obtained. In the last case, polymer layers were obtained with thickness up to several tens of microns, still active for block copolymerization.

KW - Atom transfer radical polymerization (ATRP)

KW - Biocompatibility

KW - Films

KW - Surface polymerization

U2 - 10.1002/1521-3927(20020401)23:7<417::AID-MARC417>3.0.CO;2-3

DO - 10.1002/1521-3927(20020401)23:7<417::AID-MARC417>3.0.CO;2-3

M3 - Article

SN - 1521-3927

VL - 23

SP - 417

EP - 422

JO - Macromolecular rapid communications

JF - Macromolecular rapid communications

IS - 7

ER -

Thick coating and functionalization of organic surfaces via ATRP in water

Abstract

Keywords

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