Abstract
The first synthesis of the inositol-containing marine glycolipid dioctadecanoyl discoside is reported. The key glycosylation reaction proceeds with β-selectivity at reduced temperature. The separable anomers could be readily progressed to afford discoside, its peracetate and the unnatural β-derivatives.
Original language | English |
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Pages (from-to) | 3099-3102 |
Number of pages | 3 |
Journal | SYNLETT |
Issue number | 19 |
DOIs | |
Publication status | Published - 2009 |
Keywords
- Glycolipid
- Glycosylation
- Inositol
- Mannose
- Marine sponge