Thieme chemistry journal awardees - where are they now? synthesis of the marine glycolipid dioctadecanoyl discoside

Gordon J. Florence, Tashfeen Aslam, Gavin J. Miller, Gavin D S Milne, Stuart J. Conway

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The first synthesis of the inositol-containing marine glycolipid dioctadecanoyl discoside is reported. The key glycosylation reaction proceeds with β-selectivity at reduced temperature. The separable anomers could be readily progressed to afford discoside, its peracetate and the unnatural β-derivatives.
    Original languageEnglish
    Pages (from-to)3099-3102
    Number of pages3
    JournalSYNLETT
    Issue number19
    DOIs
    Publication statusPublished - 2009

    Keywords

    • Glycolipid
    • Glycosylation
    • Inositol
    • Mannose
    • Marine sponge

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