Abstract
The multi-gram scale syntheses of the first 1,3,5-triazacyclohexane imido complexes [Ti(NR)(R3′tach)Cl2] (R=But, C6H3Pr2i-2,6; R′=Me, But) are described together with the X-ray structures of [Ti(NBut)(Me3tach)Cl2] and [Ti(NBut)(Bu3ttach)Cl2]; the complexes of Me3tach exhibit dynamic NMR behaviour ia an unusual trigonal twist of the facially coordinated Me3tach ligand (Me3tach and Bu3ttach=1,3,5-trimethyl- and tri-tert-butyl-1,3,5-triazacyclohexane, respectively).
| Original language | English |
|---|---|
| Pages (from-to) | 271-273 |
| Number of pages | 3 |
| Journal | New Journal of Chemistry |
| Volume | 23 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 1999 |
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CCDC 120616: Experimental Crystal Structure Determination
Wilson, P. (Contributor), Cooke, P. A. (Contributor), Blake, A. (Contributor), Mountford, P. (Contributor) & Schroder, M. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 1999
DOI: 10.5517/cc41hvh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc41hvh&sid=DataCite
Dataset
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CCDC 120615: Experimental Crystal Structure Determination
Wilson, P. (Contributor), Cooke, P. A. (Contributor), Blake, A. (Contributor), Mountford, P. (Contributor) & Schroder, M. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 1999
DOI: 10.5517/cc41htg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc41htg&sid=DataCite
Dataset