TY - JOUR
T1 - Towards nanostructured arrays of single molecule magnets
T2 - New Fei9 oxyhydroxide clusters displaying high ground state spins and hysteresis f
AU - Goodwill, Jeremy C.
AU - Sessoli, Roberta
AU - Gatteschi, Dante
AU - Wernsdorfer, Wolfgang
AU - Powell, Annie K.
AU - Heath, Sarah L.
PY - 2000
Y1 - 2000
N2 - Ligands of general formula N(CHRCH2OH)(CH2CO2H)2 have been used to capture portions of the Fe(OH)2+ lattice to give particles containing up to nineteen magnetically coupled iron(in) centres. If R = Me or Et, lattices containing only Fe,9 clusters result and single crystal X-ray diffraction shows that these are arranged in tilted stacks. These clusters act as single molecule magnets, pointing the way forward to engineering ordered arrays of magnetic particles. The packing of such materials is independent of the counter anion, NO3 or Cl, used.
AB - Ligands of general formula N(CHRCH2OH)(CH2CO2H)2 have been used to capture portions of the Fe(OH)2+ lattice to give particles containing up to nineteen magnetically coupled iron(in) centres. If R = Me or Et, lattices containing only Fe,9 clusters result and single crystal X-ray diffraction shows that these are arranged in tilted stacks. These clusters act as single molecule magnets, pointing the way forward to engineering ordered arrays of magnetic particles. The packing of such materials is independent of the counter anion, NO3 or Cl, used.
UR - http://www.scopus.com/inward/record.url?scp=33746509016&partnerID=8YFLogxK
U2 - 10.1039/b002135k
DO - 10.1039/b002135k
M3 - Article
AN - SCOPUS:33746509016
SN - 1470-479X
SP - 1835
EP - 1840
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 12
ER -