Transmitting information along oligo-para-phenylenes: 1,12-Stereochemical control in a terphenyl tetracarboxamide

Jonathan Clayden; Lluís Vallverdú; Madeleine Helliwell

doi:10.1039/b701682d

Transmitting information along oligo-para-phenylenes: 1,12-Stereochemical control in a terphenyl tetracarboxamide

Jonathan Clayden
, Lluís Vallverdú
, Madeleine Helliwell

Research output: Contribution to journal › Article › peer-review

Abstract

Amide-substituted terphenyls adopt a well-defined conformation that allows the transmission of stereochemical information from a controlling centre to a reaction site 11 bond lengths away, providing a model of how extended polymeric systems might be used to communicate binary information. © The Royal Society of Chemistry.

Original language	English
Pages (from-to)	2357-2359
Number of pages	2
Journal	Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/b701682d
Publication status	Published - 2007

Keywords

MOLECULAR SIGNAL-TRANSDUCTION
AROMATIC AMIDES
CONFORMATIONAL
TRANSMISSION
OXAZOLIDINE FORMATION
ASYMMETRIC INDUCTION
ATROPISOMERIC AMIDES
DYNAMIC RESOLUTION
STEREOCONTROL
(-)-EPHEDRINE
COMMUNICATION

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10.1039/b701682d

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@article{1fef01f108b243798822043e0fe445a5,

title = "Transmitting information along oligo-para-phenylenes: 1,12-Stereochemical control in a terphenyl tetracarboxamide",

abstract = "Amide-substituted terphenyls adopt a well-defined conformation that allows the transmission of stereochemical information from a controlling centre to a reaction site 11 bond lengths away, providing a model of how extended polymeric systems might be used to communicate binary information. {\textcopyright} The Royal Society of Chemistry.",

keywords = "MOLECULAR SIGNAL-TRANSDUCTION, AROMATIC AMIDES, CONFORMATIONAL, TRANSMISSION, OXAZOLIDINE FORMATION, ASYMMETRIC INDUCTION, ATROPISOMERIC AMIDES, DYNAMIC RESOLUTION, STEREOCONTROL, (-)-EPHEDRINE, COMMUNICATION",

author = "Jonathan Clayden and Llu{\'i}s Vallverd{\'u} and Madeleine Helliwell",

note = "Clayden, Jonathan Vallverdu, Lluis Helliwell, Madeleine 27 ROYAL SOC CHEMISTRY CAMBRIDGE 176RZ",

year = "2007",

doi = "10.1039/b701682d",

language = "English",

pages = "2357--2359",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - Transmitting information along oligo-para-phenylenes: 1,12-Stereochemical control in a terphenyl tetracarboxamide

AU - Clayden, Jonathan

AU - Vallverdú, Lluís

AU - Helliwell, Madeleine

N1 - Clayden, Jonathan Vallverdu, Lluis Helliwell, Madeleine 27 ROYAL SOC CHEMISTRY CAMBRIDGE 176RZ

PY - 2007

Y1 - 2007

N2 - Amide-substituted terphenyls adopt a well-defined conformation that allows the transmission of stereochemical information from a controlling centre to a reaction site 11 bond lengths away, providing a model of how extended polymeric systems might be used to communicate binary information. © The Royal Society of Chemistry.

AB - Amide-substituted terphenyls adopt a well-defined conformation that allows the transmission of stereochemical information from a controlling centre to a reaction site 11 bond lengths away, providing a model of how extended polymeric systems might be used to communicate binary information. © The Royal Society of Chemistry.

KW - MOLECULAR SIGNAL-TRANSDUCTION

KW - AROMATIC AMIDES

KW - CONFORMATIONAL

KW - TRANSMISSION

KW - OXAZOLIDINE FORMATION

KW - ASYMMETRIC INDUCTION

KW - ATROPISOMERIC AMIDES

KW - DYNAMIC RESOLUTION

KW - STEREOCONTROL

KW - (-)-EPHEDRINE

KW - COMMUNICATION

U2 - 10.1039/b701682d

DO - 10.1039/b701682d

M3 - Article

SN - 1359-7345

SP - 2357

EP - 2359

JO - Chemical Communications

JF - Chemical Communications

IS - 23

ER -

Transmitting information along oligo-para-phenylenes: 1,12-Stereochemical control in a terphenyl tetracarboxamide

Abstract

Keywords

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