Tricarbonyl(h6-chlorobenzene)chromium.

Alan K Brisdon; Ian R. Crossley; Robin G. Pritchard; John E. Warren

Tricarbonyl(h6-chlorobenzene)chromium.

Alan K Brisdon, Ian R. Crossley, Robin G. Pritchard, John E. Warren

Research output: Contribution to journal › Article › peer-review

Abstract

Crystals of the title compd. are orthorhombic, space group P212121, with a 7.1159(6), b 10.7627(11), c 12.1055(10) .ANG.; Z = 4, dc = 1.781; R = 0.056. Rw(F2) = 0.097 for 2071 reflections. It adopts a classic piano-stool structure, with the Cr(CO)3 tripod assuming a syn-eclipsed conformation relative to the arene ring (j = 2.0 Deg). The extended structure is dominated by intermol. p...H interactions (H...ring centroid 2.94 .ANG.) and nonclassical H bonds between carbonyl and arene moieties (O...H 2.50-2.58 .ANG.). [on SciFinder (R)]

Original language	English
Journal	Acta Crystallographica, Section C: Crystal Structure Communications
Volume	C59
Publication status	Published - 2003

Keywords

Crystal structure; Hydrogen bond; Molecular structure (of chromium carbonyl chlorobenzene complex)

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@article{2f9bc79040024b1a8dd956580926c36a,

title = "Tricarbonyl(h6-chlorobenzene)chromium.",

abstract = "Crystals of the title compd. are orthorhombic, space group P212121, with a 7.1159(6), b 10.7627(11), c 12.1055(10) .ANG.; Z = 4, dc = 1.781; R = 0.056. Rw(F2) = 0.097 for 2071 reflections. It adopts a classic piano-stool structure, with the Cr(CO)3 tripod assuming a syn-eclipsed conformation relative to the arene ring (j = 2.0 Deg). The extended structure is dominated by intermol. p...H interactions (H...ring centroid 2.94 .ANG.) and nonclassical H bonds between carbonyl and arene moieties (O...H 2.50-2.58 .ANG.). [on SciFinder (R)]",

keywords = "Crystal structure; Hydrogen bond; Molecular structure (of chromium carbonyl chlorobenzene complex)",

author = "Brisdon, {Alan K} and Crossley, {Ian R.} and Pritchard, {Robin G.} and Warren, {John E.}",

year = "2003",

language = "English",

volume = "C59",

journal = "Acta Crystallographica, Section C: Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Tricarbonyl(h6-chlorobenzene)chromium.

AU - Brisdon, Alan K

AU - Crossley, Ian R.

AU - Pritchard, Robin G.

AU - Warren, John E.

PY - 2003

Y1 - 2003

N2 - Crystals of the title compd. are orthorhombic, space group P212121, with a 7.1159(6), b 10.7627(11), c 12.1055(10) .ANG.; Z = 4, dc = 1.781; R = 0.056. Rw(F2) = 0.097 for 2071 reflections. It adopts a classic piano-stool structure, with the Cr(CO)3 tripod assuming a syn-eclipsed conformation relative to the arene ring (j = 2.0 Deg). The extended structure is dominated by intermol. p...H interactions (H...ring centroid 2.94 .ANG.) and nonclassical H bonds between carbonyl and arene moieties (O...H 2.50-2.58 .ANG.). [on SciFinder (R)]

AB - Crystals of the title compd. are orthorhombic, space group P212121, with a 7.1159(6), b 10.7627(11), c 12.1055(10) .ANG.; Z = 4, dc = 1.781; R = 0.056. Rw(F2) = 0.097 for 2071 reflections. It adopts a classic piano-stool structure, with the Cr(CO)3 tripod assuming a syn-eclipsed conformation relative to the arene ring (j = 2.0 Deg). The extended structure is dominated by intermol. p...H interactions (H...ring centroid 2.94 .ANG.) and nonclassical H bonds between carbonyl and arene moieties (O...H 2.50-2.58 .ANG.). [on SciFinder (R)]

KW - Crystal structure; Hydrogen bond; Molecular structure (of chromium carbonyl chlorobenzene complex)

M3 - Article

SN - 1600-5759

VL - C59

JO - Acta Crystallographica, Section C: Crystal Structure Communications

JF - Acta Crystallographica, Section C: Crystal Structure Communications

ER -

Tricarbonyl(h6-chlorobenzene)chromium.

Abstract

Keywords

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