Hazoor A. Shad, M. Azad Malik, M. Nawaz Tahir, Zahid H. Chohan, Khalid H. Thebo, Madeleine Helliwell

    Research output: Contribution to journalArticlepeer-review


    The title compound, [Bi(C8H18PS2) 3], contains a BiIII cation surrounded by three bis-(2-methyl-prop-yl)dithio-phosphinate anions, leading to a distorted octa-hedral coordination for the heavy metal. The Bi - S and S - P bond lengths are in the ranges 2.7694 (18)-2.8391 (17) and 2.019 (2)-2.035 (2) Å, respectively. The crystal structure is consolidated by C - H⋯S hydrogen bonds. Intra-molecular C - H⋯π inter-actions also play a role in stabilizing the mol-ecules.
    Original languageEnglish
    Pages (from-to)m605
    JournalActa Crystallographica Section E: Structure Reports Online
    Issue number6
    Publication statusPublished - 2010


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