Tris[bis-(2-methyl-prop-yl)dithio-phosphinato]bis-muth(III)

Hazoor A. Shad; M. Azad Malik; M. Nawaz Tahir; Zahid H. Chohan; Khalid H. Thebo; Madeleine Helliwell

doi:10.1107/S1600536810015618

Tris[bis-(2-methyl-prop-yl)dithio-phosphinato]bis-muth(III)

Hazoor A. Shad, M. Azad Malik, M. Nawaz Tahir, Zahid H. Chohan, Khalid H. Thebo, Madeleine Helliwell

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Bi(C8H18PS2) 3], contains a BiIII cation surrounded by three bis-(2-methyl-prop-yl)dithio-phosphinate anions, leading to a distorted octa-hedral coordination for the heavy metal. The Bi - S and S - P bond lengths are in the ranges 2.7694 (18)-2.8391 (17) and 2.019 (2)-2.035 (2) Å, respectively. The crystal structure is consolidated by C - H⋯S hydrogen bonds. Intra-molecular C - H⋯π inter-actions also play a role in stabilizing the mol-ecules.

Original language	English
Pages (from-to)	m605
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	6
DOIs	https://doi.org/10.1107/S1600536810015618
Publication status	Published - 2010

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title = "Tris[bis-(2-methyl-prop-yl)dithio-phosphinato]bis-muth(III)",

abstract = "The title compound, [Bi(C8H18PS2) 3], contains a BiIII cation surrounded by three bis-(2-methyl-prop-yl)dithio-phosphinate anions, leading to a distorted octa-hedral coordination for the heavy metal. The Bi - S and S - P bond lengths are in the ranges 2.7694 (18)-2.8391 (17) and 2.019 (2)-2.035 (2) {\AA}, respectively. The crystal structure is consolidated by C - H⋯S hydrogen bonds. Intra-molecular C - H⋯π inter-actions also play a role in stabilizing the mol-ecules.",

author = "Shad, {Hazoor A.} and Malik, {M. Azad} and Tahir, {M. Nawaz} and Chohan, {Zahid H.} and Thebo, {Khalid H.} and Madeleine Helliwell",

year = "2010",

doi = "10.1107/S1600536810015618",

language = "English",

volume = "66",

pages = "m605",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Tris[bis-(2-methyl-prop-yl)dithio-phosphinato]bis-muth(III)

AU - Shad, Hazoor A.

AU - Malik, M. Azad

AU - Tahir, M. Nawaz

AU - Chohan, Zahid H.

AU - Thebo, Khalid H.

AU - Helliwell, Madeleine

PY - 2010

Y1 - 2010

N2 - The title compound, [Bi(C8H18PS2) 3], contains a BiIII cation surrounded by three bis-(2-methyl-prop-yl)dithio-phosphinate anions, leading to a distorted octa-hedral coordination for the heavy metal. The Bi - S and S - P bond lengths are in the ranges 2.7694 (18)-2.8391 (17) and 2.019 (2)-2.035 (2) Å, respectively. The crystal structure is consolidated by C - H⋯S hydrogen bonds. Intra-molecular C - H⋯π inter-actions also play a role in stabilizing the mol-ecules.

AB - The title compound, [Bi(C8H18PS2) 3], contains a BiIII cation surrounded by three bis-(2-methyl-prop-yl)dithio-phosphinate anions, leading to a distorted octa-hedral coordination for the heavy metal. The Bi - S and S - P bond lengths are in the ranges 2.7694 (18)-2.8391 (17) and 2.019 (2)-2.035 (2) Å, respectively. The crystal structure is consolidated by C - H⋯S hydrogen bonds. Intra-molecular C - H⋯π inter-actions also play a role in stabilizing the mol-ecules.

U2 - 10.1107/S1600536810015618

DO - 10.1107/S1600536810015618

M3 - Article

SN - 1600-5368

VL - 66

SP - m605

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

Tris[bis-(2-methyl-prop-yl)dithio-phosphinato]bis-muth(III)

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