Two Open-Framework Germanates with Nickel Complexes Incorporated into the Framework

Shiliang Huang; Kirsten Christensen; Maxim V Peskov; Sihai Yang; Kuo Li; Xiaodong Zou; Junliang Sun

doi:10.1021/ic2013478

Two Open-Framework Germanates with Nickel Complexes Incorporated into the Framework

Shiliang Huang, Kirsten Christensen, Maxim V Peskov, Sihai Yang, Kuo Li, Xiaodong Zou, Junliang Sun

The University of Manchester

Research output: Contribution to journal › Article › peer-review

Abstract

Two open-framework germanates, SUT-1 and SUT-2, have been synthesized under hydrothermal conditions using ethylenediamine (en, H2NCH2CH2NH2) as templates and Ni(NO3)2·6H2O as the transition-metal source. Their frameworks are built with Ge10 clusters and [Ni(en)2]2+ complexes. In both structures, Ge10 clusters form square nets in the a?c plane, while the [Ni(en)2]2+ complexes bridge the square nets via Ni?O?Ge bonds to form 3D networks. They present the first examples to incorporate Ni2+ complexes into the germanate frameworks. In SUT-2, additional linkages by Ge2O7 clusters between the square nets generate a new type of topology.

Original language	English
Pages (from-to)	9921-9923
Number of pages	3
Journal	Inorganic Chemistry: including bioinorganic chemistry
Volume	50
Issue number	20
DOIs	https://doi.org/10.1021/ic2013478
Publication status	Published - 2011

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10.1021/ic2013478

http://dx.doi.org/10.1021/ic2013478

CCDC 856858: Experimental Crystal Structure Determination
Huang, S. (Contributor), Christensen, K. (Contributor), Peskov, M. V. (Contributor), Yang, S. (Contributor), Li, K. (Contributor), Zou, X. (Contributor) & Sun, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccxrmlv, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxrmlv&sid=DataCite
Dataset
CCDC 856859: Experimental Crystal Structure Determination
Huang, S. (Contributor), Christensen, K. (Contributor), Peskov, M. V. (Contributor), Yang, S. (Contributor), Li, K. (Contributor), Zou, X. (Contributor) & Sun, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccxrmmw, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxrmmw&sid=DataCite
Dataset

Cite this

@article{005e915a07d34768b71eb93a86699fe6,

title = "Two Open-Framework Germanates with Nickel Complexes Incorporated into the Framework",

abstract = "Two open-framework germanates, SUT-1 and SUT-2, have been synthesized under hydrothermal conditions using ethylenediamine (en, H2NCH2CH2NH2) as templates and Ni(NO3)2·6H2O as the transition-metal source. Their frameworks are built with Ge10 clusters and [Ni(en)2]2+ complexes. In both structures, Ge10 clusters form square nets in the a?c plane, while the [Ni(en)2]2+ complexes bridge the square nets via Ni?O?Ge bonds to form 3D networks. They present the first examples to incorporate Ni2+ complexes into the germanate frameworks. In SUT-2, additional linkages by Ge2O7 clusters between the square nets generate a new type of topology.",

author = "Shiliang Huang and Kirsten Christensen and Peskov, \{Maxim V\} and Sihai Yang and Kuo Li and Xiaodong Zou and Junliang Sun",

year = "2011",

doi = "10.1021/ic2013478",

language = "English",

volume = "50",

pages = "9921--9923",

journal = "Inorganic Chemistry: including bioinorganic chemistry ",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "20",

}

TY - JOUR

T1 - Two Open-Framework Germanates with Nickel Complexes Incorporated into the Framework

AU - Huang, Shiliang

AU - Christensen, Kirsten

AU - Peskov, Maxim V

AU - Yang, Sihai

AU - Li, Kuo

AU - Zou, Xiaodong

AU - Sun, Junliang

PY - 2011

Y1 - 2011

N2 - Two open-framework germanates, SUT-1 and SUT-2, have been synthesized under hydrothermal conditions using ethylenediamine (en, H2NCH2CH2NH2) as templates and Ni(NO3)2·6H2O as the transition-metal source. Their frameworks are built with Ge10 clusters and [Ni(en)2]2+ complexes. In both structures, Ge10 clusters form square nets in the a?c plane, while the [Ni(en)2]2+ complexes bridge the square nets via Ni?O?Ge bonds to form 3D networks. They present the first examples to incorporate Ni2+ complexes into the germanate frameworks. In SUT-2, additional linkages by Ge2O7 clusters between the square nets generate a new type of topology.

AB - Two open-framework germanates, SUT-1 and SUT-2, have been synthesized under hydrothermal conditions using ethylenediamine (en, H2NCH2CH2NH2) as templates and Ni(NO3)2·6H2O as the transition-metal source. Their frameworks are built with Ge10 clusters and [Ni(en)2]2+ complexes. In both structures, Ge10 clusters form square nets in the a?c plane, while the [Ni(en)2]2+ complexes bridge the square nets via Ni?O?Ge bonds to form 3D networks. They present the first examples to incorporate Ni2+ complexes into the germanate frameworks. In SUT-2, additional linkages by Ge2O7 clusters between the square nets generate a new type of topology.

U2 - 10.1021/ic2013478

DO - 10.1021/ic2013478

M3 - Article

SN - 0020-1669

VL - 50

SP - 9921

EP - 9923

JO - Inorganic Chemistry: including bioinorganic chemistry

JF - Inorganic Chemistry: including bioinorganic chemistry

IS - 20

ER -

Two Open-Framework Germanates with Nickel Complexes Incorporated into the Framework

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Datasets

CCDC 856858: Experimental Crystal Structure Determination

CCDC 856859: Experimental Crystal Structure Determination

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