Two Prime or not Two Prime

Andrew Spencer; Rocio  Lopez Rodriguez; Igor Larrosa

doi:10.1038/s41929-018-0097-2

Two Prime or not Two Prime

Andrew Spencer
, Rocio Lopez Rodriguez
, Igor Larrosa

Research output: Contribution to journal › Article › peer-review

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Abstract

The carboxylation of aromatic compounds with CO2 is an attractive reaction, albeit limited in scope. Now, bulky ligands in a Rh(II) catalysed C–H carboxylation of 2-arylphenols are shown to override the standard ortho/para Kolbe-Schmitt-type regioselectivity allowing instead carboxylation at 2’

Original language	English
Journal	Nature Catalysis
Volume	1
Early online date	12 Jun 2018
DOIs	https://doi.org/10.1038/s41929-018-0097-2
Publication status	Published - 2018

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10.1038/s41929-018-0097-2

Larrosa - Nature Catalysis - accepted (2)Accepted author manuscript, 96 KB

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abstract = "The carboxylation of aromatic compounds with CO2 is an attractive reaction, albeit limited in scope. Now, bulky ligands in a Rh(II) catalysed C–H carboxylation of 2-arylphenols are shown to override the standard ortho/para Kolbe-Schmitt-type regioselectivity allowing instead carboxylation at 2{\textquoteright}",

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AU - Larrosa, Igor

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AB - The carboxylation of aromatic compounds with CO2 is an attractive reaction, albeit limited in scope. Now, bulky ligands in a Rh(II) catalysed C–H carboxylation of 2-arylphenols are shown to override the standard ortho/para Kolbe-Schmitt-type regioselectivity allowing instead carboxylation at 2’

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U2 - 10.1038/s41929-018-0097-2

DO - 10.1038/s41929-018-0097-2

M3 - Article

VL - 1

JO - Nature Catalysis

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ER -

Two Prime or not Two Prime

Abstract

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