Ultra-selective, ultra-clean 1D rotating-frame Overhauser effect spectroscopy

Emma Louise Gates; Marshall Smith; Jonathan Bradley; Myron Johnson; Göran Widmalm; Mathias Nilsson; Gareth A Morris; Ralph W. Adams; Laura Castañar

doi:10.1039/D3CC00550J

Ultra-selective, ultra-clean 1D rotating-frame Overhauser effect spectroscopy

Emma Louise Gates, Marshall Smith, Jonathan Bradley, Myron Johnson, Göran Widmalm, Mathias Nilsson, Gareth A Morris, Ralph W. Adams, Laura Castañar

Research output: Contribution to journal › Article › peer-review

Abstract

An ultra-selective 1D NMR experiment – GEMSTONE-ROESY – enables clear, unambiguous assignment of ROE signals in the not uncommon situation that traditional selective methods fail. Its usefulness is demonstrated in the analysis of the natural products cyclosporin and lacto-N-difucohexaose I, providing detailed insight into the structure and conformation of these molecules.

Original language	English
Journal	Chemical Communications
Early online date	3 Apr 2023
DOIs	https://doi.org/10.1039/D3CC00550J
Publication status	E-pub ahead of print - 3 Apr 2023

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10.1039/D3CC00550JLicence: CC BY

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title = "Ultra-selective, ultra-clean 1D rotating-frame Overhauser effect spectroscopy",

abstract = "An ultra-selective 1D NMR experiment – GEMSTONE-ROESY – enables clear, unambiguous assignment of ROE signals in the not uncommon situation that traditional selective methods fail. Its usefulness is demonstrated in the analysis of the natural products cyclosporin and lacto-N-difucohexaose I, providing detailed insight into the structure and conformation of these molecules.",

author = "Gates, {Emma Louise} and Marshall Smith and Jonathan Bradley and Myron Johnson and G{\"o}ran Widmalm and Mathias Nilsson and Morris, {Gareth A} and Adams, {Ralph W.} and Laura Casta{\~n}ar",

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language = "English",

journal = "Chemical Communications",

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AU - Gates, Emma Louise

AU - Smith, Marshall

AU - Bradley, Jonathan

AU - Johnson, Myron

AU - Widmalm, Göran

AU - Nilsson, Mathias

AU - Morris, Gareth A

AU - Adams, Ralph W.

AU - Castañar, Laura

PY - 2023/4/3

Y1 - 2023/4/3

N2 - An ultra-selective 1D NMR experiment – GEMSTONE-ROESY – enables clear, unambiguous assignment of ROE signals in the not uncommon situation that traditional selective methods fail. Its usefulness is demonstrated in the analysis of the natural products cyclosporin and lacto-N-difucohexaose I, providing detailed insight into the structure and conformation of these molecules.

AB - An ultra-selective 1D NMR experiment – GEMSTONE-ROESY – enables clear, unambiguous assignment of ROE signals in the not uncommon situation that traditional selective methods fail. Its usefulness is demonstrated in the analysis of the natural products cyclosporin and lacto-N-difucohexaose I, providing detailed insight into the structure and conformation of these molecules.

U2 - 10.1039/D3CC00550J

DO - 10.1039/D3CC00550J

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Ultra-selective, ultra-clean 1D rotating-frame Overhauser effect spectroscopy

Abstract

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