Unified theory of the electronic Stark effect in molecular crystals

R. W. Munn

doi:10.1016/0301-0104(83)85037-X

Unified theory of the electronic Stark effect in molecular crystals

R. W. Munn^*

^*Corresponding author for this work

Australian National University

Research output: Contribution to journal › Article › peer-review

Abstract

A compact expression for the energy of an assembly of polar polarizable molecules in an external electric field is derived with the help of the inverse dielectric function. The expression leads to an economical derivation of the energy shifts and splittings in the electronic Stark effect in molecular crystals. Previous results are unified by verifying their equivalence and correctness.

Original language	English
Pages (from-to)	243-248
Number of pages	6
Journal	Chemical Physics
Volume	76
Issue number	2
DOIs	https://doi.org/10.1016/0301-0104(83)85037-X
Publication status	Published - 15 Apr 1983

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abstract = "A compact expression for the energy of an assembly of polar polarizable molecules in an external electric field is derived with the help of the inverse dielectric function. The expression leads to an economical derivation of the energy shifts and splittings in the electronic Stark effect in molecular crystals. Previous results are unified by verifying their equivalence and correctness.",

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AB - A compact expression for the energy of an assembly of polar polarizable molecules in an external electric field is derived with the help of the inverse dielectric function. The expression leads to an economical derivation of the energy shifts and splittings in the electronic Stark effect in molecular crystals. Previous results are unified by verifying their equivalence and correctness.

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Unified theory of the electronic Stark effect in molecular crystals

Abstract

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