Unprecedented Hexagonal Bipyramidal Single-Ion Magnets Based on Metallacrowns

Nicholas Chilton; Quan-Wen Li; Rui-Chen Wan; Yan-Cong Chen; Jun-Liang Liu; Long-Fei Wang; Jian-Hua Jia; Ming-Liang Tong

doi:10.1039/C6CC06924J

Unprecedented Hexagonal Bipyramidal Single-Ion Magnets Based on Metallacrowns

Nicholas Chilton, Quan-Wen Li, Rui-Chen Wan, Yan-Cong Chen, Jun-Liang Liu, Long-Fei Wang, Jian-Hua Jia, Ming-Liang Tong

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Abstract

Two Ln(III) (Ln = Ce or Nd) complexes based on [15-MC-6] (MC = metallacrown) and phosphine oxide are first reported with Ln(III) ion featuring a hexagonal bipyramidal LnO8 geometry, namely D6h symmetry. Magnetic susceptibilities analyses reveal both behave as single-ion magnets (SIMs), providing a new model for insight into magneto-structural correlations.

Original language	English
Journal	Chemical Communications
Early online date	21 Oct 2016
DOIs	https://doi.org/10.1039/C6CC06924J
Publication status	Published - 2016

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Text_CC-COM-08-2016-006924_AAMAccepted author manuscript, 5.03 MB

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title = "Unprecedented Hexagonal Bipyramidal Single-Ion Magnets Based on Metallacrowns",

abstract = "Two Ln(III) (Ln = Ce or Nd) complexes based on [15-MC-6] (MC = metallacrown) and phosphine oxide are first reported with Ln(III) ion featuring a hexagonal bipyramidal LnO8 geometry, namely D6h symmetry. Magnetic susceptibilities analyses reveal both behave as single-ion magnets (SIMs), providing a new model for insight into magneto-structural correlations.",

author = "Nicholas Chilton and Quan-Wen Li and Rui-Chen Wan and Yan-Cong Chen and Jun-Liang Liu and Long-Fei Wang and Jian-Hua Jia and Ming-Liang Tong",

year = "2016",

doi = "10.1039/C6CC06924J",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Unprecedented Hexagonal Bipyramidal Single-Ion Magnets Based on Metallacrowns

AU - Chilton, Nicholas

AU - Li, Quan-Wen

AU - Wan, Rui-Chen

AU - Chen, Yan-Cong

AU - Liu, Jun-Liang

AU - Wang, Long-Fei

AU - Jia, Jian-Hua

AU - Tong, Ming-Liang

PY - 2016

Y1 - 2016

N2 - Two Ln(III) (Ln = Ce or Nd) complexes based on [15-MC-6] (MC = metallacrown) and phosphine oxide are first reported with Ln(III) ion featuring a hexagonal bipyramidal LnO8 geometry, namely D6h symmetry. Magnetic susceptibilities analyses reveal both behave as single-ion magnets (SIMs), providing a new model for insight into magneto-structural correlations.

AB - Two Ln(III) (Ln = Ce or Nd) complexes based on [15-MC-6] (MC = metallacrown) and phosphine oxide are first reported with Ln(III) ion featuring a hexagonal bipyramidal LnO8 geometry, namely D6h symmetry. Magnetic susceptibilities analyses reveal both behave as single-ion magnets (SIMs), providing a new model for insight into magneto-structural correlations.

U2 - 10.1039/C6CC06924J

DO - 10.1039/C6CC06924J

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Unprecedented Hexagonal Bipyramidal Single-Ion Magnets Based on Metallacrowns

Abstract

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