Unprecedented rate enhancements of hydrogen-atom transfer to a manganese(v)-oxo corrolazine complex

Katharine A. Prokop; Sam P. De Visser; David P. Goldberg

doi:10.1002/anie.201001172

Unprecedented rate enhancements of hydrogen-atom transfer to a manganese(v)-oxo corrolazine complex

Katharine A. Prokop, Sam P. De Visser, David P. Goldberg

Research output: Contribution to journal › Article › peer-review

Abstract

Chemical equation presented Runaway reactivity: A manganese(V)-oxo porphyrinoid complex displays an unprecedented increase in reaction rate for a hydrogen-atom abstraction upon addition of anionic axial ligands (X=F - and CN-; see scheme). Density functional theory calculations are in excellent agreement with experiment, and provide insight into the origins of these remarkable axial ligand effects. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	5091-5095
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	30
DOIs	https://doi.org/10.1002/anie.201001172
Publication status	Published - 12 Jul 2010

Keywords

Hydrogen-atom transfer
Ligand effects
Manganese
Metalloenzymes
Porphyrinoids

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title = "Unprecedented rate enhancements of hydrogen-atom transfer to a manganese(v)-oxo corrolazine complex",

abstract = "Chemical equation presented Runaway reactivity: A manganese(V)-oxo porphyrinoid complex displays an unprecedented increase in reaction rate for a hydrogen-atom abstraction upon addition of anionic axial ligands (X=F - and CN-; see scheme). Density functional theory calculations are in excellent agreement with experiment, and provide insight into the origins of these remarkable axial ligand effects. {\textcopyright} 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",

keywords = "Hydrogen-atom transfer, Ligand effects, Manganese, Metalloenzymes, Porphyrinoids",

author = "Prokop, {Katharine A.} and {De Visser}, {Sam P.} and Goldberg, {David P.}",

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T1 - Unprecedented rate enhancements of hydrogen-atom transfer to a manganese(v)-oxo corrolazine complex

AU - Prokop, Katharine A.

AU - De Visser, Sam P.

AU - Goldberg, David P.

PY - 2010/7/12

Y1 - 2010/7/12

N2 - Chemical equation presented Runaway reactivity: A manganese(V)-oxo porphyrinoid complex displays an unprecedented increase in reaction rate for a hydrogen-atom abstraction upon addition of anionic axial ligands (X=F - and CN-; see scheme). Density functional theory calculations are in excellent agreement with experiment, and provide insight into the origins of these remarkable axial ligand effects. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - Chemical equation presented Runaway reactivity: A manganese(V)-oxo porphyrinoid complex displays an unprecedented increase in reaction rate for a hydrogen-atom abstraction upon addition of anionic axial ligands (X=F - and CN-; see scheme). Density functional theory calculations are in excellent agreement with experiment, and provide insight into the origins of these remarkable axial ligand effects. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - Hydrogen-atom transfer

KW - Ligand effects

KW - Manganese

KW - Metalloenzymes

KW - Porphyrinoids

U2 - 10.1002/anie.201001172

DO - 10.1002/anie.201001172

M3 - Article

SN - 1433-7851

VL - 49

SP - 5091

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 30

ER -

Unprecedented rate enhancements of hydrogen-atom transfer to a manganese(v)-oxo corrolazine complex

Abstract

Keywords

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