Abstract
Visible-light photoredox catalysis enables the synthesis of
biologically relevant isoxazolines and isoxazoles from
hydroxyimino acids. The process shows broad functional group
compatibility and mechanisitic and computational studies support
a visible-light-mediated generation of nitrile oxides by two
sequential oxidative single electron transfer processes.
biologically relevant isoxazolines and isoxazoles from
hydroxyimino acids. The process shows broad functional group
compatibility and mechanisitic and computational studies support
a visible-light-mediated generation of nitrile oxides by two
sequential oxidative single electron transfer processes.
Original language | English |
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Journal | Chemical Communications- Royal Society of Chemistry |
Early online date | 21 Sept 2016 |
DOIs | |
Publication status | Published - 2016 |