Visible-Light-Mediated Reactions of Electrophilic Radicals with Vi-nyl and Allyl Trifluoroborates

Daniel Fernández Reina; Alessandro Ruffoni; Yasair S.S Al-Faiyz; Nadeem Sheikh; Daniele Leonori

doi:10.1021/acscatal.7b01120

Visible-Light-Mediated Reactions of Electrophilic Radicals with Vi-nyl and Allyl Trifluoroborates

Daniel Fernández Reina, Alessandro Ruffoni, Yasair S.S Al-Faiyz, Nadeem Sheikh, Daniele Leonori

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Abstract

Visible-light photoredox catalysis enables the vinylation and allylation of electrophilic radicals with readily available potassium trifluoroborate reagents. The processes show good functional group compatibility, and mechanistic and computational studies have elucidated some of the aspects associated with the key radical addition step.

Original language	English
Pages (from-to)	4126-4130
Number of pages	5
Journal	ACS Catalysis
Volume	2017
Issue number	6
Early online date	15 May 2017
DOIs	https://doi.org/10.1021/acscatal.7b01120
Publication status	Published - 2017

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ACS Catal. Paper - FinalAccepted author manuscript, 1.2 MB

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@article{cf3a3937050d4cf1bf904e2b16d41289,

title = "Visible-Light-Mediated Reactions of Electrophilic Radicals with Vi-nyl and Allyl Trifluoroborates",

abstract = "Visible-light photoredox catalysis enables the vinylation and allylation of electrophilic radicals with readily available potassium trifluoroborate reagents. The processes show good functional group compatibility, and mechanistic and computational studies have elucidated some of the aspects associated with the key radical addition step.",

author = "{Fern{\'a}ndez Reina}, Daniel and Alessandro Ruffoni and Al-Faiyz, {Yasair S.S} and Nadeem Sheikh and Daniele Leonori",

year = "2017",

doi = "10.1021/acscatal.7b01120",

language = "English",

volume = "2017",

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journal = "ACS Catalysis",

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publisher = "American Chemical Society",

number = "6",

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T1 - Visible-Light-Mediated Reactions of Electrophilic Radicals with Vi-nyl and Allyl Trifluoroborates

AU - Fernández Reina, Daniel

AU - Ruffoni, Alessandro

AU - Al-Faiyz, Yasair S.S

AU - Sheikh, Nadeem

AU - Leonori, Daniele

PY - 2017

Y1 - 2017

N2 - Visible-light photoredox catalysis enables the vinylation and allylation of electrophilic radicals with readily available potassium trifluoroborate reagents. The processes show good functional group compatibility, and mechanistic and computational studies have elucidated some of the aspects associated with the key radical addition step.

AB - Visible-light photoredox catalysis enables the vinylation and allylation of electrophilic radicals with readily available potassium trifluoroborate reagents. The processes show good functional group compatibility, and mechanistic and computational studies have elucidated some of the aspects associated with the key radical addition step.

U2 - 10.1021/acscatal.7b01120

DO - 10.1021/acscatal.7b01120

M3 - Article

SN - 2155-5435

VL - 2017

SP - 4126

EP - 4130

JO - ACS Catalysis

JF - ACS Catalysis

IS - 6

ER -

Visible-Light-Mediated Reactions of Electrophilic Radicals with Vi-nyl and Allyl Trifluoroborates

Abstract

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