Zeolitic rectification of electrochemical ion transfer

Robert A W Dryfe; Stuart M. Holmes

doi:10.1016/S0022-0728(99)00506-9

Zeolitic rectification of electrochemical ion transfer

Research output: Contribution to journal › Article › peer-review

Abstract

The modification of the water|1,2-dichloroethane interface with a zeolite membrane is studied. The application of a potential difference across the modified interface allows the selective transfer of ionic species on the basis of the applied interface potential difference and the dimensions of the transferring ion with respect to those of the zeolite pores. The complete exclusion of certain ions from microporous materials at the liquid|liquid interface can be achieved, with the size of transferring species as the crucial parameter.

Original language	English
Pages (from-to)	144-149
Number of pages	5
Journal	Journal of Electroanalytical Chemistry
Volume	483
Issue number	1
DOIs	https://doi.org/10.1016/S0022-0728(99)00506-9
Publication status	Published - 30 Mar 2000

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title = "Zeolitic rectification of electrochemical ion transfer",

abstract = "The modification of the water|1,2-dichloroethane interface with a zeolite membrane is studied. The application of a potential difference across the modified interface allows the selective transfer of ionic species on the basis of the applied interface potential difference and the dimensions of the transferring ion with respect to those of the zeolite pores. The complete exclusion of certain ions from microporous materials at the liquid|liquid interface can be achieved, with the size of transferring species as the crucial parameter.",

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AU - Dryfe, Robert A W

AU - Holmes, Stuart M.

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AB - The modification of the water|1,2-dichloroethane interface with a zeolite membrane is studied. The application of a potential difference across the modified interface allows the selective transfer of ionic species on the basis of the applied interface potential difference and the dimensions of the transferring ion with respect to those of the zeolite pores. The complete exclusion of certain ions from microporous materials at the liquid|liquid interface can be achieved, with the size of transferring species as the crucial parameter.

U2 - 10.1016/S0022-0728(99)00506-9

DO - 10.1016/S0022-0728(99)00506-9

M3 - Article

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VL - 483

SP - 144

EP - 149

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1

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Zeolitic rectification of electrochemical ion transfer

Abstract

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