Abstract
Stabilized AlHCl2·(THF)2 hydroaluminates RCCH with exceptional chemo-, regio- and stereoselectivity under efficient ZrCl 2(η-C5Me5)2 catalysis (2-5 mol%). The resulting vinyl alanes undergo palladium cross-coupling with a wide range of sp2 electrophiles (aryl, heteroaryl and vinyl halides/pseudohalides) in good to excellent yields.
Original language | English |
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Pages (from-to) | 1488-1490 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 49 |
Issue number | 15 |
DOIs | |
Publication status | Published - 21 Feb 2013 |
Keywords
- Vinyl chloride
- Alkynes
- Palladium
- Polyvinyl chloride