The Synthesis and Structural Characterisation of a Series of Iodides and Dipyridyl Ketone based Metal Complexes with relevance to the Grätzel Photovoltaic cell and Single Molecule Magnets.

  • Farhad Haghjoo

Student thesis: Phd

Abstract

The Grätzel photovoltaic cell is described in the introductory chapter and the main experimental method used in this study, X-ray crystallography, in the second chapter.The work described in chapter 3 and 4 was inspired by the Grätzel cell namely, the synthesis and characterisation of iodide and poly-iodides in chapter 3 and transition metal complexes synthesised using 2,2'-dipyridyl ketone in chapter 4.Chapter five looks in detail at a series of tri-angular lanthanide complexes, a chance discovery made while synthesising the 2,2'-dipyridyl ketone complexes described in chapter 4. These tri-angular clusters have interesting magnetic properties that are also described.
Date of Award1 Aug 2014
Original languageEnglish
Awarding Institution
  • The University of Manchester
SupervisorRobin Pritchard (Supervisor)

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