Hydrogen bonding plays an important role in the formation of crystal structures. The workwas carried out for the search of novel perhydrates. Six combinations were used usingdifferent stoichiometric quantities of guanidine cations, trimesate and hydrogen peroxide.Six potentially new novel perhydrates were discovered using X-ray powder diffraction.Structure of three novel perhydrates, e.g. Na3(C9H3O6).1.5H2O2.3H2O, Na2(NH4)4(CH6N3)3(C9H3O6). 2.5H2O2.12.5H2O and (CH6N3)3(C9H3O6).1.26H2O2.0.72H2O were fully determinedusing Single-Crystal X-ray diffraction.
| Date of Award | 3 Jan 2014 |
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| Original language | English |
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| Awarding Institution | - The University of Manchester
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| Supervisor | Robin Pritchard (Supervisor) |
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X-ray Studies of Novel Perhydrates
Saleem, A. (Author). 3 Jan 2014
Student thesis: Master of Science by Research